HPLC Separation of Triacylglycerol Positional Isomers on a Polymeric ODS Column

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HPLC separation of triacylglycerol positional isomers on a polymeric ODS column.

A polymeric ODS column was applied to the resolution of triacylglycerol positional isomers (TAG-PI), i.e. 1,3-dioleoyl-2-palmitoyl-glycerol (OPO) and 1,2-dioleoyl-3-palmitoyl-rac-glycerol (OOP), with a recycle HPLC system. To investigate the ODS column species and the column temperatures for the resolution of a TAG-PI pair, a mixture of OPO and OOP was subjected to an HPLC system equipped with ...

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Characterization of non-endcapped polymeric ODS column for the separation of triacylglycerol positional isomers.

The characteristics of a non-endcapped polymeric ODS column for the resolution of triacylglycerol positional isomers (TAG-PI) were examined using a recycle HPLC-atmospheric pressure chemical ionization/mass spectrometry system. A pair of TAG-PI containing saturated fatty acids at least 12 carbons was separated. Except for TAG-PI containing elaidic acid, pairs of TAG-PI containing three unsatura...

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ژورنال

عنوان ژورنال: Analytical Sciences

سال: 2008

ISSN: 0910-6340,1348-2246

DOI: 10.2116/analsci.24.865